
The Dutch side were under pressure for the whole game as Napoli dominated possession and peppered their goal but Dani de Wit scored in the 57th minute for a stunning victory in Group F.
Arsenal, who have not claimed a European trophy since lifting the old Cup Winners’ Cup in 1994, went behind at Rapid Vienna but defender David Luiz and striker Pierre-Emerick Aubameyang struck late goals for a 2-1 Group B win.
AS Roma also managed to come back from a goal down to beat Swiss side Young Boys 2-1 away thanks to two goals in five second-half minutes by Bruno Peres and Marash Kumbulla to get their Group A campaign off to a winning start.
Bayer Leverkusen went on the rampage against French side Nice in a 6-2 victory that saw winger Karim Bellarabi score twice late on for the home side in Group C.
Spanish clubs Granada and Real Sociedad enjoyed 2-1 and 1-0 away wins over PSV Eindhoven and Croatian side Rijeka in Group E and F respectively, while Benfica chalked up a 4-2 victory over Lech Poznan and Rangers won 2-0 at Standard Liege in Group D.